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Change default location of OST file Outlook Exchange
For Outlook 2016
https://support.microsoft.com/en-us/help/2752583/you-cannot-change-the-location-of-the-offline-outlook-data-file-ost-in
Copy the existing .ost file to the new location that you want to use. If you want to create a new .ost file isntead, you can skip this step.
Open Control Panel. Open the Mail applet.
Click Show Profiles → Add
Add the Exchange account using email address and password.
Stay in the Add Account window after successfully adding.
Tick the Change account settings box → Next
Click More Settings…* → Outlook Data file Settings…
* Click Browse then browse to the OST file you copied in step one or the location you want the OST in.
* Type the name for the new OST file and click Open → Finish
For Outlook 2007 to 2013