====== How to Determine Existing Drive Letters in Windows ======
http://www.computerhope.com/issues/ch000854.htm
:!: These commands may require Windows Vista and newer versons of Windows.
===== Command Prompt =====
Using WMI:
wmic logicaldisk get name
or, even better:
wmic logicaldisk get caption,providername,drivetype,volumename
===== Powershell =====
Assuming you are on windows 7 or have installed Powershell:
gwmi win32_LogicalDisk -filter DriveType=4